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Design of TRIP Steel With High Welding and Galvanizing Performance in Light of Thermodynamics and Kinetics

LI Lin , DE COOMAN B C , LIU Rendong , VLEUGELS J , ZHANG Mei , SHI Wen

钢铁研究学报(英文版)

A new type of transformation induced plasticity (TRIP) steel with not only high strength and high ductility but also superior welding and galvanizing properties was designed and developed recently. Low carbon and low silicon content were preliminarily selected with the aim of meeting the requirements of superior quality in both welding and galvanizing. Phosphorus was chosen as one of the alloying elements, because it could reduce carbon activity in cementite and increase the stability of austenite. In addition, the possibility of phosphorus segregating at grain boundary was also discussed by thermodynamics as well as kinetics. Phase diagram was estimated at high temperature and the composition of the steel was then selected in the hyperperitectic range to avoid problems, which might occur in sheet steel continuous casting. Phase diagram in the intercritical temperature was estimated for the steel to obtain the starting temperature of fast cooling. For understanding the minimum rate of fast cooling, pearlite growth kinetics was calculated with selfdeveloped diffusion coefficients of elements in grain boundary. Overaging temperature was determined through the calculation of T0 temperature by both equilibrium and paraequilibrium assumptions, which was different from the current determination, which is only based on an equilibrium estimation.

关键词: TRIP steel;design;thermodynamics;kinetics;weldability;galvanization property

Viscosities Behavior of CaO-SiO2-MgO-Al2O3 Slag With Low Mass Ratio of CaO to SiO2 and Wide Range of Al2O3 Content

TANG Xu-long , ZHANG Zuo-tai , GUO Min , ZHANG Mei , WANG Xi-dong

钢铁研究学报(英文版)

The present paper is aimed at recycling of coal ash and blast furnace slag to produce mineral wool. Considering the mineralogical constitutions of coal ash and blast furnace slag, the primary quaternary slag compositions of CaO-SiO2-MgO-Al2O3 with basicity (mass ratio of CaO to SiO2) ranging from 05 to 09 and alumina ranging from 5% to 20% were investigated through a rotating cylinder method. The experimental results indicated that the viscosities decreased with increasing basicity above the liquidus temperature, and increased with increasing alumina content, and the maximum values were reached and as the alumina content was 20%, followed by the decrease with further increasing alumina content due to its amphoteric behavior. The amphoteric behavior of Al2O3 also performed in the relationship between viscosity and non-bridging oxygen per tetrahedrally-coordinated atom (NBO/T), and the viscosities decreased with increasing the NBO/T except the slag with a basicity 05 and Al2O3 20% which have a low NBO/T value and a low viscosity than others.-

关键词: viscosity , mineral wool , NBO/T , slag-

Weldability of Low Carbon Transformation Induced Plasticity Steel

ZHANG Mei , LI Lin , FU Renyu , ZHANG Jicheng , WAN Zi

钢铁研究学报(英文版)

Transformation induced plasticity (TRIP) steel exhibited high or rather high carbon equivalent (CE) because of its chemical composition, which was a particularly detrimental factor affecting weldability of steels. Thus the weldability of a TRIP steel (grade 600) containing (in mass percent, %) 011C119Si167Mn was extensively studied. The mechanical properties and impact toughness of butt joint, the welding crack susceptibility of weld and heat affected zone (HAZ) for tee joint, control thermal severity (CTS) of the welded joint, and Y shape 60° butt joint were measured after the gas metal arc welding (GMAW) test. The tensile strength of the weld was higher than 700 MPa. Both in the fusion zone (FZ) and HAZ for butt joint, the impact toughness was much higher than 27 J, either at room temperature or at -20 ℃, indicating good low temperature impact ductility of the weld of TRIP 600 steel. In addition, welding crack susceptibility tests revealed that weldments were free of surface crack and other imperfection. All experimental results of this steel showed fairly good weldability. For application, the crossmember in automobile made of this steel exhibited excellent weldability, and fatigue and durability tests were also accomplished for crossmember assembly.

关键词: TRIP steel;weldability;welding crack susceptibility;mechanical property;impact toughness

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